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Spectroscopic Characterization of Intermediates in the Urate Oxidase Reaction †

✍ Scribed by Kahn, Kalju; Tipton, Peter A.


Book ID
125986600
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
226 KB
Volume
37
Category
Article
ISSN
0006-2960

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Theoretical Study of Intermediates in th
✍ Kalju Kahn 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 215 KB

The energetics of the urate oxidase reaction has been studied employing HF, MP2, and DFT calculations. Gas-phase energies of possible urate oxidase reaction intermediates were calculated; radical species and dehydrourate had high relative energies while 5-hydroperoxyisourate was stable in the gas ph