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Identification of the True Product of the Urate Oxidase Reaction

โœ Scribed by Kahn, Kalju; Serfozo, Peter; Tipton, Peter A.

Book ID
120499118
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
253 KB
Volume
119
Category
Article
ISSN
0002-7863

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Theoretical Study of Intermediates in th
Theoretical Study of Intermediates in the Urate Oxidase Reaction
โœ Kalju Kahn ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 215 KB

The energetics of the urate oxidase reaction has been studied employing HF, MP2, and DFT calculations. Gas-phase energies of possible urate oxidase reaction intermediates were calculated; radical species and dehydrourate had high relative energies while 5-hydroperoxyisourate was stable in the gas ph