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Spectroscopic and structural studies of complexes of the fac-[Re(N∩N)(CO)3L]n+ type (N∩N=2-(2-pyridyl)benzothiazole; L=Cl, Br, CF3SO3 −, CH3CN)

✍ Scribed by Xiaoyuan Chen; Frank J Femia; John W Babich; Jon Zubieta

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
105 KB
Volume
314
Category
Article
ISSN
0020-1693

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## Abstract A series of new rhenium(I) complexes of the type [Re^I^(CO)~3~(L)(L′)]^__n__+^ (L = 2,2′‐biquinoline (bqui) or 3,3′‐(ethane‐1,2‐diyl)‐2,2′‐biquinoline (CH~2~CN~2~)bqui); L′ = CF~3~SO$\rm{\_3^ - }$, pyridine (py), or 4‐substituted pyridine (HOpy, Bzpy, or NCpy); __n__ = 0 or 1) were prep