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Synthesis, characterization and structure of the first rhenium compound of di-2-pyridyl ketone thiophene-2-carboxylic acid hydrazone (dpktah), fac-[Re(CO)3(N,N-κ2-dpktah)Cl]

✍ Scribed by Mohammed Bakir; Colin Gyles


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
757 KB
Volume
918
Category
Article
ISSN
0022-2860

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Rhenium tricarbonyl chloro of di-2-pyrid
✍ Mohammed Bakir; Orville Green 📂 Article 📅 2011 🏛 Elsevier Science 🌐 English ⚖ 709 KB

The reaction between di-2-pyridyl ketone 4-aminobenzoylhydrazone hydrate (dpk4abh.H 2 O) and [Re(CO) 5 Cl] in refluxing toluene gave fac-[Re(CO) 3 (j 2 -N,N-dpk4abh)Cl]. Hydrolysis of fac-[Re(CO) 3 (j 2 -N,N-dpk4abh)Cl] to form fac-[Re(CO) 3 (j 3 -N,O,N-dpkO,OH)] occurs in wet solvents. The identity