Spectrophotometric determination of manganese with 2-oximinocyclohexanone thiosemicarbazone
✍ Scribed by F.Salinas López; J.C.Jiménez Sánchez; T.Galeano Díaz
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 238 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0026-265X
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A highly selective spectrophotometric method is described for the determination of palladium, using 3-thiophenaldehyde-4-phenyl-3-thiosemicarbazone (TAPS). The method is based on the formation of an insoluble palladium(II)-TAPS complex, which is extractable into chloroform from \(1 M\) sulfuric acid
A flow-injection manifold has been developed for the spectrophotometric determination of manganese(VII) at 548 nm after extraction into chloroform of the ion-associate, benzyltributylammonium permanganate. The carrier stream was a pH 6 buffer containing 10% (w/v) ammonium fluoride and the reagent st