Spectrophotometric Determination of Iron with 2-Oximinocyclohexane Thiosemicarbazone
✍ Scribed by F. Salinas; J. C. Jiménez Sánchez; M. M. Lozano Ruiz
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 115 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0037-9646
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A highly selective spectrophotometric method is described for the determination of palladium, using 3-thiophenaldehyde-4-phenyl-3-thiosemicarbazone (TAPS). The method is based on the formation of an insoluble palladium(II)-TAPS complex, which is extractable into chloroform from \(1 M\) sulfuric acid
1,2,3-Cyclohexanetrione-l,2-dioxime-3-thiosemicarbazone CTDT), produces coloured complexes with zinc and cadmium ions in basic medium. The yellow coiour obtained has been used to develop spectro hotome ric methods for zinc and cadmium in the concentration range 1.30-8.5Opg ml-I of zinc and A new met