𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Spectral moments of solvated electrons

✍ Scribed by Ian Carmichael

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
304 KB
Volume
56
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

A moment theory analysis is performed on the optical absorption spectra of surplus electrons localized in various media. The deduced attnbutes of the excess particle are compared with those obtained by a perturbation treatment of the exact ground state solution of a currently popular model potential for the species. Several frequency dependent observables are evaluated and a source of inadequacy in the current theory, the presence of a Coulomb tail, is revealed.

πŸ“œ SIMILAR VOLUMES

Time-resolved spectroscopy of solvated e
Time-resolved spectroscopy of solvated electrons
✍ L.D. Zusman; A.B. Helman πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 373 KB

The theory of timedependent transient spectra of solvated electrons is developed. It is shown that the evolution of the spectral line centre reproduces the time dependence of the classical correlation function of the random process of electronic energy level fluctuations. The results of this invest

Direct observations of solvated electron
Direct observations of solvated electrons in liquid hydrocarbons
✍ J.T. Richards; J.K. Thomas πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 English βš– 503 KB

Using the techniques of pulse radiolysis a short-lived transient absorbing species (Xrnax = 1500 run] has been observed in liquid hydrocarbons at 193%. This absorption has been assigned to a trapped or sofvated electron and a&olute reaction rates have been obtained for reactions of sohated electrons