A moment theory analysis is performed on the optical absorption spectra of surplus electrons localized in various media. The deduced attnbutes of the excess particle are compared with those obtained by a perturbation treatment of the exact ground state solution of a currently popular model potential
Time-resolved spectroscopy of solvated electrons
β Scribed by L.D. Zusman; A.B. Helman
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 373 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The theory of timedependent transient spectra of solvated electrons is developed. It is shown that the evolution of the spectral line centre reproduces the time dependence of the classical correlation function of the random process of electronic energy level fluctuations.
The results of this investigation are compared with experiment.
π SIMILAR VOLUMES
Electron-Zeeman (EZ) resolved electron paramagnetic resonance (EPR) spectroscopy is introduced. In this two-dimensional pulse EPR technique a sinusoidal external field βB 0 (t) of variable amplitude is applied during the pulse sequence, resulting in a fieldswept EPR spectrum that is spread into a se