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Spectral assignments for 1H,13C and 15N solution and solid-state NMR spectra of s-tetrazine and dihydro-s-tetrazine derivatives

✍ Scribed by Pascal Palmas; Elzéar Girard; Eric Pasquinet; Thomas Caron; Didier Poullain

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
377 KB
Volume
45
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Tetrazine‐based organic species are interesting intermediates for organic synthesis and represent a source of new materials bearing specific properties with potential applications in biology and material science. ^1^H, ^13^C, ^15^N NMR measurements carried out in solution and in the solid‐state have been used to characterize a series of 3,6‐disubstituted 1,2,4,5‐tetrazine/dihydrotetrazine new derivatives. Experimental results presented here provide data for the assignment of ^15^N chemical shifts including new organic small molecules; two polymers having the tetrazine ring in the main chain and several previously published compounds. We report apparently for the first time ^15^N experimental chemical shift data for tetrazine systems in the solid state. Copyright © 2007 John Wiley & Sons, Ltd.

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