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Specific Ion Effects || The Determination of Specific Ion Structure by Neutron Scattering and Computer Simulation

โœ Scribed by Kunz, Werner


Book ID
125943908
Publisher
WORLD SCIENTIFIC
Year
2009
Tongue
English
Weight
681 KB
Edition
2
Category
Article
ISBN
9814271586

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โœฆ Synopsis


Specific ion effects are important in numerous fields of science and technology. They have been discussed for over 100 years, ever since the pioneering work done by Franz Hofmeister and his group in Prague. Over the last decades, hundreds of examples have been published and periodically explanations have been proposed. However, it is only recently that a profound understanding of the basic effects and their reasons could be achieved. Today, we are not far from a general explanation of specific ion effects. This book summarizes the main new ideas that have come up in the last ten years.In this book, the efforts of theoreticians are substantially supported by the experimental results stemming from new and exciting techniques. Both the new theoretical concepts and the experimental landmarks are collected and critically discussed by eminent scientists and well-known specialists in this field. Beyond the rigorous explanations, guidelines are given to non-specialists in order to help them understand the general rules governing specific ion effects in chemistry, biology, physics and engineering.


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Ionized vinylamine: a specific reagent f
โœ Guy Bouchoux; Jean-Yves Salpin ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 183 KB ๐Ÿ‘ 1 views

The use of ionized vinylamine [CH 2 = CHNH 2 ] + . in locating double bonds in olefinic compounds is illustrated on a series of octene molecules. It is demonstrated that a cyclobutanation process leads to intense diagnostic ions which unambiguously allow the position of the C = C bond on the aliphat