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Specific Effects in Acid Catalysis by Ion Exchange Resins. IV. The Effect of Quaternary Ammonium Ions on the Hydrolysis of Esters of Related Structure 1

โœ Scribed by Riesz, Peter; Hammett, Louis P.

Book ID
121491562
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
389 KB
Volume
76
Category
Article
ISSN
0002-7863

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โœ Thomas H. Fife; M.P. Pujari ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 207 KB

Rate constants have been determined for hydrolysis of the acetate, glutarate, and phthalate monoesters of 2-hydroxy-1,10-phenanthroline in water at 30 degrees C and &mgr = 0.1 M with KCl. The hydrolysis reactions of the esters are hydroxide ion catalyzed at pH > 9. The phthalate and glutarate monoes