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Ionized vinylamine: a specific reagent for the determination of olefinic bond position by ion/molecule reactions

✍ Scribed by Guy Bouchoux; Jean-Yves Salpin

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
183 KB
Volume
11
Category
Article
ISSN
0951-4198

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✦ Synopsis

The use of ionized vinylamine [CH 2 = CHNH 2 ] + . in locating double bonds in olefinic compounds is illustrated on a series of octene molecules. It is demonstrated that a cyclobutanation process leads to intense diagnostic ions which unambiguously allow the position of the C = C bond on the aliphatic chain to be determined. The described experiments were carried out in a Fourier transform ion cyclotron resonance mass spectrometer. Under these conditions high reaction efficiencies and pronounced regioselectivity are observed.

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