Specific-cation medium effects in the oxidation of ascorbic acid by hexachloroiridate(IV) and hexabromoiridate(IV)
β Scribed by Drury, William D.; Dekorte, John M.
- Book ID
- 126973624
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 674 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The kinetics of the redox reaction between mandelic acid (MA) and ceric sulfate have been studied in aqueous sulfuric acid solutions and in HzSO4-MC104 (M+ = H+, Li+, Na+) and HzS04-MHS04 (M+ = Li+, Na+, K+) mixtures under various experimental conditions of total electrolyte concentration (that is,
## Abstract The kinetics of the oxidation of styrene, cinnamic acid, and some of their substituted derivatives by hexachloroiridate(IV) in dimethyl formamideβwater mixtures and in the presence of perchloric acid have been investigated. The reactions appear to proceed via the formation of an unstabl