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Some remarks on the calculations of hyperfine splittings in the ESR spectra of conjugated radicals

✍ Scribed by Jan Wasilewski; Wiesław Woźnicki


Publisher
Springer
Year
1972
Tongue
English
Weight
441 KB
Volume
23
Category
Article
ISSN
1432-2234

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📜 SIMILAR VOLUMES


29Si hyperfine splittings in the EPR spe
✍ John. N. C. Walton 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 390 KB

The 29Si satellites were observed in the EPR spectra of 3-trimethylsilylprop-2-yny1, 1-trimethylsiloxyprop-2-ynyl and trimethylsiloxymethyl radicals. Comparison of the experimental values with spin densities calculated by semi-empirical MO methods led to a value of 810 G for Qsi. The magnitude and p