Solvent effect on the esr hyperfine splitting constants of some phenoxyl radicals
✍ Scribed by Y. O¯ishi; K. Mukai; H. Nishiguchi; Y. Deguchi; H. Takaki
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 97 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
We have studied the solvent effect on the ESR hyperfine splitting constants of some neutral radicals.
📜 SIMILAR VOLUMES
TheaN and a;H hyperfine splitting constants of pyridinyl are poorly reproduced by INDO molecular orbital calculations if assuming a planar geometry for the radical. A much better agreement with experiment has been found by evaluating: these constants from vibronic ~avef~n~tions even though at a ~mjq
## Abstract The effects of solvent dielectric response on the isotropic hyperfine coupling constants of the 1,4‐benzoquinone, 1,4‐naphthoquinone and 9,10‐anthraquinone anions and 1,4‐naphthalenediol cation radicals were studied by electron spin resonance (ESR) spectroscopy and by the theoretical de