We have studied the solvent effect on the ESR hyperfine splitting constants of some neutral radicals.
An ESR on formation of iminoxy free radicals—solvent effect on hyperfine splitting constants
✍ Scribed by Piotr J. Chmielewski; Adam Jezierski; Zdzisław Sitecki; Jacek Sienkiewicz
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 450 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0969-806X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
TheaN and a;H hyperfine splitting constants of pyridinyl are poorly reproduced by INDO molecular orbital calculations if assuming a planar geometry for the radical. A much better agreement with experiment has been found by evaluating: these constants from vibronic ~avef~n~tions even though at a ~mjq
The role played by solvent in the reactions of organic molecules is not well understood. One is often tempted to try to interpret solvent effects on processes in which ions or molecules are formed solely in terms of solvent interactions with an ionic or radical-like transition state to the neglect o