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Isotropic hyperfine splitting at the fluorine nucleus in the EPR spectra of free radicals

✍ Scribed by P. V. Schastnev; G. M. Zhidomirov


Publisher
SP MAIK Nauka/Interperiodica
Year
1965
Tongue
English
Weight
348 KB
Volume
5
Category
Article
ISSN
0022-4766

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29Si hyperfine splittings in the EPR spe
✍ John. N. C. Walton πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 English βš– 390 KB

The 29Si satellites were observed in the EPR spectra of 3-trimethylsilylprop-2-yny1, 1-trimethylsiloxyprop-2-ynyl and trimethylsiloxymethyl radicals. Comparison of the experimental values with spin densities calculated by semi-empirical MO methods led to a value of 810 G for Qsi. The magnitude and p