Polarity Contributions to Hyperfine Spli
✍
Derek Marsh
📂
Article
📅
2002
🏛
Elsevier Science
🌐
English
⚖ 108 KB
A self-consistent treatment of reaction field effects on isotropic (14)N hyperfine coupling constants of nitroxide spin labels in mixtures of polar and apolar solvents is given based on the Onsager approach. It is shown that this works reasonably well for mixtures of water or methanol with dioxane,