Some Reactions of Amino Acid N-Carboxy Anhydrides
β Scribed by Kopple, Kenneth D.
- Book ID
- 120445646
- Publisher
- American Chemical Society
- Year
- 1957
- Tongue
- English
- Weight
- 653 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The polymerization of -y-benzyl+glutamate NCA initiated by n-hexylamine in DMF proceeds with two successive propagation r a h whose ratio is about 1.5. The onset of the increase in rate of propagation occurred a t a DP, of 7-14, which waa independent of initiator to anhydride ratio and anhydride con
## Abstract Oligopeptides were synthesized in high yields by the controlled coupling reaction of __N__βcarboxy Ξ±βamino acid anhydrides (NCA's) with amino acid and peptide sodium salts in the heterogeneous reaction medium of acetonitrileβwater which contained sodium carbonate. In this solvent, it co