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Some observations on märkl's cyclic phosphonium salt synthesis. The synthesis of a phosphocane

✍ Scribed by Kenneth L. Marsi; Donald M. Lynch; G. David Homer

Book ID
112122632
Publisher
Journal of Heterocyclic Chemistry
Year
1972
Tongue
English
Weight
298 KB
Volume
9
Category
Article
ISSN
0022-152X

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✍ Fernando Albericio; Marta Cases; Jordi Alsina; Salvatore A. Triolo; Louis A. Car 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 293 KB

Phosphonium derivatives of HOAt such as PyAOP are useful for the solid-phase preparation of a range of peptides that include those incorporating hindered amino acids, difficult short sequences, and cyclic peptides. An advantage relative to uronium salts is that excess PyAOP does not undergo the detr