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Some mechanisms for the formation of organomagnesium and other organometallic compounds

✍ Scribed by Henry Gilman; R. E. Brown


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
203 KB
Volume
50
Category
Article
ISSN
0165-0513

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Studies of a proposed mechanism for the
✍ J. Dreux; P. Lhoste; M. Moreau; J. Royer πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 English βš– 252 KB

Part of the reaction between 2H-pyran-2-ones and organomagnesium compounds has been investigated by means of MNDO and ab initio calculations. Criteria for the mechanism of reaction are provided by the stereoselectivity observed and calculations are consistent with this stereoselectivity. Conformatio