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Studies of a proposed mechanism for the reaction between 2H-pyran-2-ones and organomagnesium compounds

✍ Scribed by J. Dreux; P. Lhoste; M. Moreau; J. Royer

Publisher: John Wiley and Sons
Year: 1985
Tongue: English
Weight: 252 KB
Volume: 6
Category: Article
ISSN: 0192-8651
DOI: 10.1002/jcc.540060104

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✦ Synopsis

Part of the reaction between 2H-pyran-2-ones and organomagnesium compounds has been investigated by means of MNDO and ab initio calculations. Criteria for the mechanism of reaction are provided by the stereoselectivity observed and calculations are consistent with this stereoselectivity. Conformations of the reaction intermediates are given.

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