Synthesis and Purification of Some Main Group Organometallic Precursors for Compound Semiconductors

Synthesis of (Indenylidene)phosphoranes

Synthesis of (Indenylidene)phosphoranes − A Novel Class of Ligand Precursors for Main-Group and Transition Metal Organometallics

✍ Konstantin A. Rufanov; Burkhard Ziemer; Markus Hummert; Stefan Schutte 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB 👁 2 views

Bridging ligands / Constrained geometry catalysts / Cyclopentadienyl ligands / Isoelectronic analogues / Isolobal relationship / Phosphoranes / Phosphorus ylides / Indenyl / Sodium IndPPh 2 (1) reacts with RCH 2 Br to form the phosphonium salts [RCH 2 P(Ph) 2 Ind] + Br -(2: R = Ph; 3: R = C 6 F 5 )