Some Free Radical Reactions of Hydrogen Chloride
โ Scribed by Raley, John H.; Rust, Frederick F.; Vaughan, William E.
- Book ID
- 125999597
- Publisher
- American Chemical Society
- Year
- 1948
- Tongue
- English
- Weight
- 450 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The gas phase photolysis of CCl, in the presence of several alkanes has been used to obtain Arrhenius parameters for the abstraction of hydrogen atoms by the cc& radical: (4) Cc1, + RH -% CRCI, + R The following log k4 values were obtained: 2,3-Dimethylbutane C -C ~H I ~ Methy lcy clohexane log k4 1
The gas phase photolysis of CP3CC13 in the presence of scveral alkanes has been used to obtain Arrhenius parameters for the abstraction of hydrogen atoms by the CF3CC12 radical : CFBCCI~ + RH -+ CF3CC12H + R Activation energies of 9.6 and 8.0 kcal/mole are found for abstraction from secondary and te