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Some Free Radical Reactions of Hydrogen Chloride

โœ Scribed by Raley, John H.; Rust, Frederick F.; Vaughan, William E.


Book ID
125999597
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
450 KB
Volume
70
Category
Article
ISSN
0002-7863

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The gas phase photolysis of CCl, in the presence of several alkanes has been used to obtain Arrhenius parameters for the abstraction of hydrogen atoms by the cc& radical: (4) Cc1, + RH -% CRCI, + R The following log k4 values were obtained: 2,3-Dimethylbutane C -C ~H I ~ Methy lcy clohexane log k4 1

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The gas phase photolysis of CP3CC13 in the presence of scveral alkanes has been used to obtain Arrhenius parameters for the abstraction of hydrogen atoms by the CF3CC12 radical : CFBCCI~ + RH -+ CF3CC12H + R Activation energies of 9.6 and 8.0 kcal/mole are found for abstraction from secondary and te