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Some electrophilic substitution reactions of 9,10-dimethyltriptycene

✍ Scribed by P. de Koe; C. de Rijke


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
160 KB
Volume
86
Category
Article
ISSN
0165-0513

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Preparation of 9,10-dimethyltriptycene
✍ P. de Koe; A. J. van Bennekom; J. Coops πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 60 KB

## Abstract The synthesis of 9,10‐dimethyltriptycene is described.

Electrophilic substitution reactions of
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Dipyrroheptanes have been reacted with a number of electrophiles, including aryldiazonium salts, acyl chlorides and isocyanates to give selectively the mono-or disubstituted derivatives. The bis(trichloroacetyl) dipyrroheptane can be used for the synthesis of amide and ester derivatives.

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THE chemistry of 7-substituted bicyclok.2. dheptanes (I) has been of considerable interest in recent years, particularly in connection with the behavior of the corresponding carbonium ions. 4 Aside from the saturated parent compounds, many unsaturated and aromatic variants have been prepared and stu