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The synthesis and reactions of some 1′-substituted 9, 10-dihydro-9, 10-methanoanthracenes

✍ Scribed by Jerrold Meinwald; Edward G. Miller

Publisher: Elsevier Science
Year: 1961
Tongue: French
Weight: 233 KB
Volume: 2
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)84056-9

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✦ Synopsis

THE chemistry of 7-substituted bicyclok.2. dheptanes (I) has been of considerable interest in recent years, particularly in connection with the behavior of the corresponding carbonium ions. 4 Aside from the saturated parent compounds, many unsaturated and aromatic variants have been prepared and studied. 4 An interesting group of compounds in this series which ' The nomenclature used in the body of this Communication has been chosen to emphasize the close chemical relationship between compounds based on skeletons I and II. Thus, compounds II (b-j) will be referred to as 7-substituted dibenzobicyclob.2. i]heptadienes rather than the IUPAC indicated 1 '-substituted 9, lo-dihydro-9, lo-methanoanthracenes.

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