Electrophilic substitution reactions of dipyrroheptane
โ Scribed by Stefaan Depraetere; Wim Dehaen
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 109 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Dipyrroheptanes have been reacted with a number of electrophiles, including aryldiazonium salts, acyl chlorides and isocyanates to give selectively the mono-or disubstituted derivatives. The bis(trichloroacetyl) dipyrroheptane can be used for the synthesis of amide and ester derivatives.
๐ SIMILAR VOLUMES
THE metal halide-catalyzed disproportionation of substituted tetraalkyl-2 RSi(CH3)3 A12Br6+ Si(CH3)4 + R2Si(CH3)2 silanes is considered to involve electrophilic substitution on carbon and nucleophilic substitution on silicon. 2 The transition state is pictured as: We have measured the initial rate