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Electrophilic substitution reactions of dipyrroheptane

โœ Scribed by Stefaan Depraetere; Wim Dehaen


Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
109 KB
Volume
44
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Dipyrroheptanes have been reacted with a number of electrophiles, including aryldiazonium salts, acyl chlorides and isocyanates to give selectively the mono-or disubstituted derivatives. The bis(trichloroacetyl) dipyrroheptane can be used for the synthesis of amide and ester derivatives.


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Structural effects in electrophilic alip
โœ Glen A. Russell; K.L. Nagpal ๐Ÿ“‚ Article ๐Ÿ“… 1961 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 171 KB

THE metal halide-catalyzed disproportionation of substituted tetraalkyl-2 RSi(CH3)3 A12Br6+ Si(CH3)4 + R2Si(CH3)2 silanes is considered to involve electrophilic substitution on carbon and nucleophilic substitution on silicon. 2 The transition state is pictured as: We have measured the initial rate