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Model Reactions for Electrophilic Substitution of Aromatic Compounds

โœ Scribed by Prof. Dr. Franz Effenberger

Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
216 KB
Volume
11
Category
Article
ISSN
0044-8249

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Recently we have had occasion to carry out a number of experiments very similar to those reported by Biswas and Chatterjee and wish to point out an important omission in their paper. We have acylated linear polystyrene (MW -100,000) using both phthalic and succinic anhydrides in nitrobenzene, and Al

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Presence of oxidizing agents, these reactions are retarded and the P-P bonds in the sulfides, whose presence was demonstrated Some years ago by X-ray structural analysis, remain unaltered. Since the P-P bonds in phosphorus oxyacids are stable in alkaline solution and in order to avoid the presence o

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Rate constants have been determined in aqueous Me 2 SO mixtures for the reaction of super-electrophilic 4,6-dinitrobenzofuroxan (DNBF) with a series of hydroxy-and methoxy-substituted benzenes whose pK a values range between -3 and -9. The study extends the reactivity range of weakly basic aromatics