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Solvomercuration-demercuration of representative olefins in the presence of acetonitrile. Convenient procedure for the synthesis of amines

✍ Scribed by Brown, Herbert Charles; Kurek, Joseph T.


Book ID
115467770
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
363 KB
Volume
91
Category
Article
ISSN
0002-7863

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Convenient procedure of Horner–Wadsworth
✍ Alessandra Lattanzi; Liliana R. Orelli; Patrizia Barone; Antonio Massa; Patrizia 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 799 KB

A mild and practical procedure of Horner-Wadsworth-Emmons olefination promoted by lithium hydroxide and a-cyano phosphonates has been set up for the synthesis of a,b-unsaturated nitriles. The reaction conditions are tolerated by functionalized ketones and the exclusive formation of E-g-hydroxy a,b-u