✦ LIBER ✦

Solvolysis of a Catalan lignite with solvents of low hydrogen donor capacity

✍ Scribed by Azael Fabregat; Jaume Giralt; Francesc Giralt

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 486 KB
Volume: 66
Category: Article
ISSN: 0016-2361
DOI: 10.1016/0016-2361(87)90133-5

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✦ Synopsis

The effect of the hydrogen donor capacity of the solvent ~ such as fuel oil, anthracene oil and mixtures of 10, 20 and 30 wt % of anthracene oil in fuel oil -on the solvolysis of a Catalan lignite was studied. Liquid yields of 50 wt % (daf) obtained by solvolysis with fuel oil were increased when the hydrogen donor capacity of the fuel oil was enhanced by the addition of anthracene oil. A linear relation was found between the maximum coal conversion and the anthracene oil content of the mixture. The yield varied exponentially with reciprocal absolute temperature for each solvent mixture studied. A simple kinetic model was fitted to the data and a solid-fuel reaction model put forward.

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