To study the nature of chemical cleavage and resultant product transfer from solid lignite phase to liquid phase, autoclave (300 cm3) experiments have been carried out at pressures ranging up to 34 MPa and temperatures of 380-390ยฐC. The charge to the autoclave was freshly mined wet lignite, tetralin and hydrogen or helium. To obtain an indication of the reaction mechanisms underlying the liquefaction process, liquid and gas samples from the reactor at different time intervals were analysed. The gas samples were analysed by use of a multi-column, multi-valve automated gas chromatograph, a system specially fabricated for coal-derived gas analysis. The liquid sample was filtered through Millipore filters and separate into three fractions by gel permeation chromatography.
Fraction1 is mostly colloidal carbon and high-molecular-weight species which cannot be separated on a g.c. Fractions 2 and 3 were analysed by gas chromatography -mass spectrometry (g.c.-m.s.). Fraction 2 represents the liquid products released from lignite and fraction 3 is mostly the tetralin and tetralin-derived products. Gel permeation chromatography (g.p.c.) followed by gas chromatography (g.c.) was used to devise a method for monitoring the extent of liquefaction. The production of carbon dioxide is at a maximum before the liquefaction reactions are at a significant rate. The source of carbon dioxide appears to be the carboxylic groups in lignite. The liquefaction reactions consume hydrogen from tetralin which undergoes dehydrogenation to form naphthalene. Once the lignite has undergone depolymerization, the tetralin to naphthalene conversion slows down. The continued heating of lignite conversion products in excess of tetralin does not appear to alter the molecular size distribution of the liquid product. The distillable fraction of lignite-derived liquid is composed of various alkylated phenols and aromatics and alkanes, and they are formed simultaneously.