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Solvent reorganization energy of electron-transfer reactions in polar solvents

✍ Scribed by Matyushov, Dmitry V.

Book ID
120289505
Publisher
American Institute of Physics
Year
2004
Tongue
English
Weight
708 KB
Volume
120
Category
Article
ISSN
0021-9606

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πŸ“œ SIMILAR VOLUMES

Electron transfer reactions in solvent m
Electron transfer reactions in solvent mixtures: the excess component of solvent reorganization free energy
✍ M. Morillo; C. Denk; P. PΓ©rez; M. LΓ³pez; A. SΓ‘nchez; R. Prado; F. SΓ‘nchez πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 215 KB

In this paper, experimental and simulation results corresponding to studies of electron transfer processes in solvent mixtures are presented. The methodology is presented to obtain the relevant parameters controlling the elementary electron transfer step, namely, the reorganization free energy, u, a

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The free energy change of an electron transfer reaction in a polar solvent is rigorously analyzed within the framework of the dielectric continuum model. An appropriate expression for the electrostatic energy between the two product ions separated by R is derived. The present result does not support