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A Failure of Continuum Theory: Temperature Dependence of the Solvent Reorganization Energy of Electron Transfer in Highly Polar Solvents

✍ Scribed by Vath, Peter; Zimmt, Matthew B.; Matyushov, Dmitry V.; Voth, Gregory A.

Book ID
120257245
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
160 KB
Volume
103
Category
Article
ISSN
0022-3654

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πŸ“œ SIMILAR VOLUMES

Electron transfer reactions in solvent m
Electron transfer reactions in solvent mixtures: the excess component of solvent reorganization free energy
✍ M. Morillo; C. Denk; P. PΓ©rez; M. LΓ³pez; A. SΓ‘nchez; R. Prado; F. SΓ‘nchez πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 215 KB

In this paper, experimental and simulation results corresponding to studies of electron transfer processes in solvent mixtures are presented. The methodology is presented to obtain the relevant parameters controlling the elementary electron transfer step, namely, the reorganization free energy, u, a