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Solvent isotope effects and the mechanism of chymotrypsin action

✍ Scribed by Kresge, A. J.


Book ID
127094902
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
417 KB
Volume
95
Category
Article
ISSN
0002-7863

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Adamantane and 1,3,5,7-tetradeuterioadamantane were oxidized by RuO, in two solvent systems, CCI,-CH,CN-H,O and acetone-water, yielding two kinetic deuterium isotope effects (KIEs), 4.8 f 0.2 and 7.8 i 0-1, respectively, very similar to those obtained in analogous reactions with cis-decalin and perd