Solvent induced conformational kinetics (sick)

✍ Scribed by Leffert Jonkman; Jan Kommandeur

• Book ID: 103010254
• Publisher: Elsevier Science
• Year: 1970
• Tongue: English
• Weight: 933 KB
• Volume: 5
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(70)85052-7

✦ Synopsis

The Netherlands Specific conformations of molecules may be induced by the solvent when a large free volume is associated with the oonformational change. The conformational energy barrier is then a property d the solvent, rather than of the molecule. Such effects are reported for several subs-d phenyl-hew&-nitroxides, where Solvent Induced Conformational KLneCics (SICK) can be studied by ESR. Energy barriers involved in conformational changea P~'B IWAY theught to be inherant to the structure of the molecule under consideration. In general, however, such barriers are meas-