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Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate

✍ Scribed by Shengjun Zhang; Shuang Gao; Zuwei Xi; Jie Xu

Book ID
119215569
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
126 KB
Volume
8
Category
Article
ISSN
1566-7367

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✍ Sandra E Martı́n; Analı́a Garrone πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 258 KB

Selective oxidation of secondary and benzylic alcohols was efficiently accomplished by H 2 O 2 under solvent-free condition catalyzed by FeBr 3 . Secondary alcohols are selectively oxidized even in the presence of primary ones. This method is high yielding, safe and operationally simple.