Solvent effects on the kinetics of solvolysis of trans-dichlorobis (N-methylethylenediamine)cobalt(III) ion in water–propan-2-ol and water–acetonitrile mixtures
✍ Scribed by Gehan Moustafa El-Subruiti
- Book ID
- 110370085
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 224 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0340-4285
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📜 SIMILAR VOLUMES
Following the kinetic investigation of the solvolysis of a range of cobalt(II1) complexes in mixtures of water + cosolvent where the cosolvent enhances the solvent structure and decreases the dielectric constant, kinetic data are now reported for such a solvolysis in water + urea where urea acts as
The kinetics of the solvolysis of the ions [Co(NH3)sC1 ] 2 + and [Co(CN)sC1] 3-have been investigated in a range of water-rich mixtures of water with n-PrOH at various temperatures. The variation of the enthalpies and entropies of activation with solvent composition show extrema in composition range
## Abstract The solvolysis of __cis__(chloro)(1‐amino‐propan‐2‐ol)bis(ethylenediamine)cobalt(III) in aqueous alcoholic media using methanol, propan‐2‐ol, __t__‐butanol as cosolvents, resulted in the formation of the (N,O) chelated product__cis__[Co(en)~2~(NH~2~CH~2~CHOHCH~3~)]^3+^. The pseudo first