Solvent effects on the initial and transition states for the solvolysis of trans-dichlorobis-(N-methylethylenediamine) cobalt(III) complex in water–dimethyl sulfoxide mixtures
✍ Scribed by Gehan M. El-Subruiti; Salah S. Massoud
- Book ID
- 110247431
- Publisher
- Springer
- Year
- 2000
- Tongue
- English
- Weight
- 91 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0340-4285
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## Abstract The kinetics of solvolysis of __trans__‐dichlorobis(__N__‐methylethylenediamine)cobalt(III) complex have been investigated in aqua‐organic solvent media (0–60% (v/v) cosolvent) at 25 ≤ t°C ≤ 60, using __n__‐propanol and __tert__‐butyl alcohol as cosolvents. The first‐order rate constant
The kinetics of the solvolytic aquation of cis-(Bromo) (imidazole) bis(ethy1enediamine) cobalt (111) and cis-(Bromo) (N-methylimidazole) bis(ethy1enediamine) cobalt(II1) have been investigated in aqueous methanol media with methanol content 0-80% by weight and a t temperatures 40-55°C. The pseudo-fi