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Solvent effects on the initial and transition states upon solvolysis oftrans-dichlorotetra(4-ethylpyridine)cobalt(III) perchlorate in water+methanol mixtures

✍ Scribed by Ibrahim M. Sidahmed; Amel M. Ismail

Publisher: Springer
Year: 1987
Tongue: English
Weight: 434 KB
Volume: 12
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf01171662

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## Abstract The kinetics of solvolysis of __trans__‐dichlorobis(__N__‐methylethylenediamine)cobalt(III) complex have been investigated in aqua‐organic solvent media (0–60% (v/v) cosolvent) at 25 ≤ t°C ≤ 60, using __n__‐propanol and __tert__‐butyl alcohol as cosolvents. The first‐order rate constant