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Kinetics of solvolysis of the trans-dichlorobis(R-ethylenediamine)cobalt(III) ion (R = N-methyl or N,N′-dimethyl) in urea–water mixtures

✍ Scribed by Gehan Moustafa El-Subruiti


Book ID
110246868
Publisher
Springer
Year
2000
Tongue
English
Weight
118 KB
Volume
25
Category
Article
ISSN
0340-4285

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Kinetics of the solvolysis of the trans-
✍ Grahame S. Groves; Cecil F. Wells 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 392 KB

Following the kinetic investigation of the solvolysis of a range of cobalt(II1) complexes in mixtures of water + cosolvent where the cosolvent enhances the solvent structure and decreases the dielectric constant, kinetic data are now reported for such a solvolysis in water + urea where urea acts as

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✍ Gehan Moustafa El-Subruiti 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB 👁 1 views

## Abstract The kinetics of solvolysis of __trans__‐dichlorobis(__N__‐methylethylenediamine)cobalt(III) complex have been investigated in aqua‐organic solvent media (0–60% (v/v) cosolvent) at 25 ≤ t°C ≤ 60, using __n__‐propanol and __tert__‐butyl alcohol as cosolvents. The first‐order rate constant