𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Solvent Effects on n → σ * Transitions of the Bases, Water, Ammonia, Hydrogen Sulfide and Phosphine

✍ Scribed by Stevenson, D. P.; Coppinger, G. M.; Forbes, J. W.


Book ID
126107189
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
376 KB
Volume
83
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Hydrogen bonding and solvent effects on
✍ Jun Zeng; Daiqian Xie 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

Our method for estimating solvent effects on electronic spectra in media with strong solute-solvent interactions is applied here to calculate the absorption and fluorescence solvatochromatic shifts of dilute triazines in water. First, the ab initio CASSCF method is used to estimate the gas-phase ele

Hydrogen-deuterium isotope effects for t
✍ P.J. Smith; S.K. Tsui 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 204 KB

In a recent publication2 the mechanism of the reaction of i-arylethyltrimethylammonium ions with ethoxide ion in ethanol at 70° was shown to be E2. The transition state for this process involved extensive proton transfer to base as exhibited by the observed trend in hydrogendeuterium isotope effects

Effect of water on proton migration in a
✍ R. De Lisi; M. Goffredi 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 777 KB

Conductance measurements at 25°C on dilute solutions of hydrochloric acid in n-butanol and iso-butanol containing small amounts of water are r e? or-ted. The data were analysed with a computer programm for the linearized 1965 theoretical Fuoss-Onsager equation. The equivalent conductance at iMnite d

Medium effects on the initial and the tr
✍ Gehan Moustafa El-Subruiti 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB 👁 1 views

## Abstract The kinetics of solvolysis of __trans__‐dichlorobis(__N__‐methylethylenediamine)cobalt(III) complex have been investigated in aqua‐organic solvent media (0–60% (v/v) cosolvent) at 25 ≤ t°C ≤ 60, using __n__‐propanol and __tert__‐butyl alcohol as cosolvents. The first‐order rate constant