## Abstract The effects of solvent on S~N~2 reaction between some substituted benzyl chlorides and chloride ion have been investigated by DFT and ab initio methods using the polarizabale continuum model. The activation energies are higher in the solution media relative to the gas phase and grow by
Solvent effects in the reaction between piperazine and benzyl bromide
β Scribed by S. Ranga Reddy; P. Manikyamba
- Book ID
- 107584384
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 2007
- Tongue
- English
- Weight
- 145 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0253-4134
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π SIMILAR VOLUMES
## Abstract The reaction of copper with benzyl bromides in dipolar aprotic solvents has been studied. There are no linear or other simple relations between Ξ΅, 1/Ξ΅, __Y__, __P__, __n__, and the rate of reaction. The activity of the solvent is determined by donor number (DN) in reaction under conside
## Abstract The kinetics of the reaction of benzyl bromide with thiourea was studied in different pure (protic and aprotic) solvents and the rate data was correlated using linear multiple regression analysis. From the regression coefficients which describe the susceptibility of rate to different so
## Abstract The rate constant for the Menschutkin reaction of 1,2βdimethylimidazole with benzyl bromide to produce 3βbenzylβ1,2βdimethylimidazolium bromide was determined in a number of ionic liquids and molecular organic solvents. The rate constants in 12 ionic liquids are in the range of (1.0β3.2