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Solvent Effect on the ET/SN2 Competition in the Reaction of a Radical Anion with Some Benzyl Bromides

✍ Scribed by Huang, Y.; Wayner, D. D. M.


Book ID
120550896
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
232 KB
Volume
116
Category
Article
ISSN
0002-7863

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Ab initio MO study of the solvent effect
✍ Osamu Kikuchi; Yoko Sano; Ohgi Takahashi; Kenji Morihashi πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 524 KB

A recently developed ab initio MO theory including solvent effects has been applied to a typical cation-anion reaction, the SN2 reaction of the trimethylsulfonium cation with the chloride anion. In the gas phase, the trimethylsulfonium and chloride ions are unstabilized, and the reaction is expected