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Solvent effect on thermodynamics of molecular equilibria

✍ Scribed by Jerzy Małecki

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
329 KB
Volume
112
Category
Article
ISSN
0009-2614

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✦ Synopsis

The solvent effect on changes in cntbalpy and entropy of mokcuktr equilibria is discussed. General relations, describing enthalpy and entropy changes of molecuhr equilibria. are proposed after assuming a form for the free-encrgst dependence on solvent polarity. A special case of the relations is derived from Onsager's dipole reaction field modeL These considerations show that the cnthalpy and entropy changes of molecular equilibria can be defined in vartrious ways and two extreme approaches arc examined.

📜 SIMILAR VOLUMES

Solvent effects on halonium ion ∡ carbon
Solvent effects on halonium ion ∡ carbonium ion equilibria
✍ Samuel P. McManus; Paul E. Peterson 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 221 KB

Although the polar bromination of alkenes has long been postulated' to involve ethylenebromonium ion intermediates, some product studies have led to suggestions2-4 of the intermediate's solvent dependence.