Compensation effect in the thermodynamics of conformational equilibria
β Scribed by A.I. Fishman; A.A. Stolov; A.B. Remizov
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 496 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1386-1425
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The solvent effect on changes in cntbalpy and entropy of mokcuktr equilibria is discussed. General relations, describing enthalpy and entropy changes of molecuhr equilibria. are proposed after assuming a form for the free-encrgst dependence on solvent polarity. A special case of the relations is der
The conformational equilibrium of 1,2-dichloroethane (DCE) in 19 different media (vapour phase, liquid, solutions in n-hexane, n-heptane, carbon tetrachloride, benzene, toluene, ethyl benzene (EB), carbon disulphide, diethyl ether, bromoform, chloroform, dichloromethane, pyridine, acetone, methanol-
## Abstract The conformational equilibrium constants for a series of 1βalkyl substituted cyclohexanols have been determined using a lanthanide shift reagent, and the results compared with other methods. In comparison to other technique greater preference is shown by the hydroxyl group for the equat