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Effect of lanthanide shift reagents on conformational equilibria

✍ Scribed by J. R. Dixon; P. S. McIntyre; I. G. Morris; D. L. Williams

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
174 KB
Volume
15
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The conformational equilibrium constants for a series of 1‐alkyl substituted cyclohexanols have been determined using a lanthanide shift reagent, and the results compared with other methods. In comparison to other technique greater preference is shown by the hydroxyl group for the equatorial position. This is rationalized by the effect on the equilibrium of the bulky shift reagent.

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