TEE nuoleophilio oharaoter of diazomethane suggests that it should react with cerbonium ions as shown in the following generalized equation.
✦ LIBER ✦
Solvent effects on halonium ion ∡ carbonium ion equilibria
✍ Scribed by Samuel P. McManus; Paul E. Peterson
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 221 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Although the polar bromination of alkenes has long been postulated' to involve ethylenebromonium ion intermediates, some product studies have led to suggestions2-4 of the intermediate's solvent dependence.
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## Abstract The reactions of stabilized carbonium ions of setoglaucin, methyl violet, and ethyl violet with cyanide ions are largely catalyzed by the cationic micelles of cetyltrimethylammonium bromide (CTAB) in aqueous media. Added counterions (anions in this case) have strong inhibitory effects o