Mechanisms of decomposition of diethyl diazosuccinate: The solvent effect on the extent of carbene and carbonium ion intermediates
β Scribed by M.T.H. Liu; O. Banjoko; Y. Yamamoto; I. Moritani
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 450 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4020
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The kinetics of the thermal decomposition of the trisoxalactocobaltate(III) complex has been investigated in the presence of EtOH and (CH2OH)2 spectrophotometrically in the 50 70 \_+ 0.1 ~ C range. The rate of the reaction decreases upon the addition of either of the alcohols to the reaction medium,
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The re3son.s for the necessity of n moditir;ltion of Germer's method for incorporating the solrent effect into the haniltonhn arc ertplJined\_ The rolvation st,!blliz.nion of the systrms F-, HF, L? and N\_Ndimethylfornumide is calculated.