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Solvent effect on the radical polymerization of di-n-butyl itaconate

โœ Scribed by Tsuneyuki Sato; Naoki Morita; Hitoshi Tanaka; Tadatoshi Ota


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
486 KB
Volume
27
Category
Article
ISSN
0887-624X

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๐Ÿ“œ SIMILAR VOLUMES


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The polymerization of diisopropyl itaconate (DIPI) initiated with dimethyl 2,2'-azobisisobutyrate(MAIB) was investigated kinetically in benzene. The polymerization rate (Rp) was expressed by R v = k[MAIB]ยฐ46[I)IPI] 16 at 50 ยฐ. The overall activation energy of the polymerization was calculated to be

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The effect of LiClO 4 on the polymerization of di-2-[2-(2-methoxyethoxy)ethoxy]ethyl itaconate (DMEI) with dimethyl 2,2-azobisisobutyrate (MAIB) was investigated in methyl ethyl ketone (MEK) kinetically and by ESR. The polymerization rate (R p ) at 50ะŠC, where the concentrations of DMEI and MAIB wer