Solvent effect on the radical polymerization of di-n-butyl itaconate
โ Scribed by Tsuneyuki Sato; Naoki Morita; Hitoshi Tanaka; Tadatoshi Ota
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 486 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0887-624X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The polymerization of diisopropyl itaconate (DIPI) initiated with dimethyl 2,2'-azobisisobutyrate(MAIB) was investigated kinetically in benzene. The polymerization rate (Rp) was expressed by R v = k[MAIB]ยฐ46[I)IPI] 16 at 50 ยฐ. The overall activation energy of the polymerization was calculated to be
The effect of LiClO 4 on the polymerization of di-2-[2-(2-methoxyethoxy)ethoxy]ethyl itaconate (DMEI) with dimethyl 2,2-azobisisobutyrate (MAIB) was investigated in methyl ethyl ketone (MEK) kinetically and by ESR. The polymerization rate (R p ) at 50ะC, where the concentrations of DMEI and MAIB wer