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Solvent dynamics and intramolecular charge transfer in4-Cyano-4′-butyloxybiphenyl (4COB).

✍ Scribed by M. van Damme; J. Hofkens; F.C. de Schryver; T.G. Ryan; W. Rettig; A. Klock

Book ID
104203166
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
599 KB
Volume
45
Category
Article
ISSN
0040-4020

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✦ Synopsis

The photophysical properties of 4-cyan-4'-butylaaybiphenyl (4COB) in diluted solutions at room temperature are reported: From this study it is clear that 4COB forms an I(nlramolecular) C(harp) T(ranafer) state . Furthermore, the influence of the temperature on the formation of the ICT state of4COB in 1-butane and diexhylether is investigated to study the role of the solvent dynamics on the stabilintion of the ICY state . Finally the importance of hydrogen bonded dusters in the stabilizadon,of tbefSa of 4COB has been esensined in 1-butanol/butyronitrile nib lures.

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